Semiconductor Chemicals
Process chemicals are critical to the semiconductor manufacturing process, as they are used to clean, etch, and deposit materials onto the surface of the semiconductor wafer. Each stage of the manufacturing process requires a specific set of chemicals, with varying degrees of purity and concentration, to achieve the desired results.
Cleaning chemicals, for instance, are used to remove impurities and contaminants from the wafer's surface before any fabrication can take place. These chemicals are typically composed of acids, bases, or solvents and can include hydrofluoric acid (HF), ammonium hydroxide (NH4OH), and hydrogen peroxide (H2O2).
Etching chemicals, on the other hand, are used to remove specific layers from the surface of the wafer to create patterns or structures. Etching can be either a wet or dry process and utilizes chemicals such as hydrochloric acid (HCl), nitric acid (HNO3), and sulfuric acid (H2SO4).
Deposition chemicals are used to add new layers of material to the wafer, and can include metal films, dielectric materials, and semiconductors. Chemical vapor deposition (CVD) and physical vapor deposition (PVD) are two common deposition techniques used in the semiconductor industry, which require different sets of chemicals.
Photoresist chemicals are used in photolithography processes to transfer patterns onto the wafer, and planarization chemicals, which are used to flatten the wafer's surface and improve yield.
The specific set of process chemicals used in semiconductor manufacturing will depend on the exact fabrication process and the materials being used. Some of the most commonly used process chemicals in semiconductor manufacturing include:
Hydrofluoric acid (HF)
Ammonium hydroxide (NH4OH)
Hydrogen peroxide (H2O2)
Hydrochloric acid (HCl)
Nitric acid (HNO3)
Sulfuric acid (H2SO4)
Silicon tetrachloride (SiCl4)
Titanium tetrachloride (TiCl4)
Phosphine (PH3)
Arsine (AsH3)
Boron trichloride (BCl3)
Trimethyl aluminum (TMA)
Tungsten hexafluoride (WF6)
Silane (SiH4)
Dichlorosilane (SiH2C12)
Other chemicals and compounds used during the semiconductor manufacturing process include:
Chemical / Compounds |
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(L)-Ethyl lactate |
1,1,1-Trichloroethane |
1,2-Dichloroethylene, all isomers |
1-Methoxy-2-propyl acetate |
1-Nitropropane |
2,2,6,6-Tetrabromobisphenol A |
2,4,6,8-Tetramethylcyclotetrasiloxane |
2-Butanone |
2-Butoxyethanol |
2-Ethoxyethanol |
2-Ethoxyethyl acetate |
2-Methoxyethanol |
2-Methylimidazole |
4-Chloro-2-methylphenol |
Acetic acid |
Acetone |
Acetonitrile |
Alloy 42 |
Aluminum |
Aluminum |
Aluminum nitride |
Aluminum phosphide |
Aluminum tris(8-hydroxyquinoline) |
Ammonia |
Ammonium fluoride |
Ammonium persulfate |
Anatase |
Antimony |
Antimony |
Antimony trichloride |
Antimony trioxide |
Argon |
Arsenic |
Arsenic pentafluoride |
Arsenic trioxide |
Arsenic trisulfide |
Arsine |
Bis(dimethylamino)dimethylsilane |
Bismuth |
Bismuth telluride |
Bismuth telluride |
Bisphenol A |
Boron |
Boron Nitride |
Boron nitride |
Boron oxide |
Boron tribromide |
Boron trichloride |
Boron trifluoride |
Borophosphosilicate glass |
Cadmium |
Cadmium oxide |
Cadmium selenide |
Cadmium sulfide |
Cadmium telluride |
Carbon tetrachloride |
Chromium |
Chromium trioxide |
Chromium(III) oxide |
Cobalt |
Cobaltic-cobaltous oxide |
Cobaltous oxide |
Colophony |
Copper |
Copper Indium Gallium Selenide (CIGS) |
Copper(II) oxide |
Cupric sulfide |
Cuprous selenide |
Cyclohexyl methacrylate |
Decaborane |
Diborane |
Dichlorosilane |
Diethanolamine |
Diethyl oxalate |
Diethylene glycol dimethyl ether |
Diethylene glycol monobutyl ether |
Diethylsilane |
Dimethyl acetamide |
Dimethyl sulfoxide |
Dimethylamine borane |
Dimethylformamide |
Dodecyl and tetradecyl glycidyl ethers |
Epichlorohydrin |
Ethanolamine |
Ethyl lactate |
Ethyl silicate |
Ethyl-3-ethoxypropionate |
Formaldehyde |
Gallium |
Gallium |
Gallium arsenide |
Gallium Manganese Arsenide (GaAs) |
Gallium nitride |
Gallium oxide |
Gallium phosphide |
Gallium trichloride |
Germanium |
Germanium dioxide |
Germanium telluride |
Germanium tetrachloride |
Germanium tetrafluoride |
Germanium tetrahydride |
Gold |
Hafnium |
Helium |
Hexachlorodisilane |
Hexafluorobutadiene |
Hexamethyldisilazane |
Hydrazine |
Hydrogen chloride |
Hydrogen fluoride |
Hydrogen peroxide |
Hydrogen selenide |
Indium |
Indium arsenide |
Indium nitride |
Indium phosphide |
Isopropyl alcohol |
Kovar |
Lead |
Lead titanate |
Lead zirconate titanate |
Lead(II) sulfide |
Lead(II) telluride |
Manganese(II) oxide |
Manganese(III) oxide |
Melamine |
Mercuric telluride |
Mercury(II) selenide |
Methyl alcohol |
Methyl cellosolve acetate |
Methyl formate |
Methylchloro-isothiazolinone |
Molybdenum disilicide |
Molybdenum Disulfide |
N-(2-Hydroxyethyl)ethylenediamine |
n-Butyl acetate |
n-Butyl alcohol |
N-Methyl-2-pyrrolidone |
Nickel |
Nickel carbonyl |
Nickel(II) oxide |
Nitric acid |
Nitrobenzene |
Nitrogen trifluoride |
Octamethyltrisiloxane |
Oxirane |
Pentaborane |
Pentaerythritol triacrylate |
Perfluoro compounds, C5-18 |
Perfluoroisobutylene |
Perfluorooctane sulfonic acid |
Perfluorotributylamine |
Perylene |
Phenol |
Phenol-formaldehyde resin |
Phosphine |
Phosphoric acid |
Phosphorus (yellow) |
Phosphorus oxychloride |
Phosphorus pentafluoride |
Phosphorus pentoxide |
Phosphorus tribromide |
Phosphorus trichloride |
Platinum silicate |
Platinum, soluble salts |
Polysilicon |
Potassium hydroxide |
Propargyl alcohol |
Quartz |
Rhenium |
Rubidium |
Sapphire |
Scandium |
Scandium nitride |
Selenium hexafluoride |
Selenourea |
Sichrome |
Silica, amorphous |
Silicic acid |
Silicon |
Silicon Carbide (SiC) |
Silicon dioxide |
Silicon nitride |
Silicon nitride |
Silicon tetrachloride |
Silicon tetrahydride |
Silver |
Sodium hydroxide |
Stibine |
Stoddard solvent |
Strontium titanate |
Sulfolane |
Sulfuric acid |
Tellurium |
tert-Butylarsine |
Tetrafluoroboric acid |
Tetramethyl ammonium hydroxide |
Tetramethylsilane |
Thallium |
Thallium selenide |
Tin |
Tin(II) oxide |
Tin(IV) oxide |
Titanium dioxide |
Titanium nitride |
Toluene |
Trichlorosilane |
Triethyl borate |
Triethylindium |
Trifluoro(tetrahydrofuran)boron |
Trimellitic anhydride |
Trimethylaluminum |
Trimethylborane |
Trimethylgallium |
Trimethylindium |
Tungsten |
Vinyltrimethylsilane |
Xylene isomers |
Zinc chloride fume |
Zinc oxide |
Zinc telluride |
Zirconium boride |